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鎸?/span>涔?/span>鐨?/span>綺?/span>鍚?/span>鍔?/span>鏄?/span>鑳?/span>綺?/span>鍓?/span>鍜?/span>娑?/span>灞?/span>鏉?/span>鏂?/span>鐨?/span>鍩?/span>鏈?/span>瑕?/span>姹?/span>錛?/span>鐗?/span>鍒?/span>鏄?/span>姘?/span>涓?/span>鎴?/span>娼?/span>婀?/span>鐜?/span>澧?/span>涓?/span>鐨?/span>綺?/span>鍚?/span>鍔?/span>灝?/span>涓?/span>閲?/span>瑕?/span>錛?/span>浣?/span>瑕?/span>瀹?/span>鐜?/span>榪?/span>涓鐐?/span>闈?/span>甯?/span>鍏?/span>鏈?/span>鎸?/span>鎴?/span>鎬?/span>銆?/span>鑱?/span>(2-涔?/span>鍩?/span>-2-鎭?/span>鍞?/span>鍟?/span>) (PEOX) 鍏?/span>鏈?/span>浣?/span>鎶?/span>灝?/span>鐜?/span>銆?/span>楂?/span>鏌?/span>闊?/span>鎬?/span>銆?/span>浣?/span>姣?/span>鎬?/span>鍜?/span>鎶?/span>铔?/span>鐧?/span>璐?/span>鐗?/span>鎬?/span>錛?/span>瀹?/span>鏃?/span>鑳?/span>澶?/span>鐢?/span>浣?/span>娑?/span>灞?/span>鏉?/span>鏂?/span>錛?/span>涔?/span>鍙?/span>浣?/span>涓?/span>鏂?/span>鐗?/span>淇?/span>澶?/span>鐢?/span>鑳?/span>綺?/span>鍓?/span>鍜?/span>鍔?/span>鍥?/span>鍓?/span>銆?/span>鐒?/span>鑰?/span>錛?/span>PEOX鍥?/span>鍏?/span>楂?/span>浜?/span>姘?/span>鎬?/span>錛?/span>鍦?/span>娼?/span>婀?/span>鐜?/span>澧?/span>涓?/span>鐨?/span>浣?/span>鐢?/span>鍙?/span>鍒?/span>闄?/span>鍒?/span>銆?/span>榪?/span>鏃?/span>錛?/span>瑗?/span>鍖?/span>宸?/span>涓?/span>澶?/span>瀛?/span>鏉?/span>鐐?/span>鍗?/span>鏁?/span>鎺?/span>璇?/span>棰?/span>緇?/span>銆?/span>鐗?/span>鎷?/span>鍗?/span>澶?/span>瀛?/span>欖?/span>縐?/span>搴?/span>鏁?/span>鎺?/span>璇?/span>棰?/span>緇?/span>鍚?/span>浣?/span>鎶?/span>閬?/span>浜?/span>涓縐?/span>鍩?/span>浜?/span>PEOX鐨?/span>鏂?/span>鍨?/span>閫?/span>鏄?/span>鑳?/span>綺?/span>鍓?/span>鈥?/span>娑?/span>灞?/span>鏉?/span>鏂?/span>錛?/span>鍦?/span>娼?/span>婀?/span>鐜?/span>澧?/span>涓?/span>鍏?/span>鏈?/span>澧?/span>寮?/span>鐨?/span>鑰?/span>姘?/span>鎬?/span>鑳?/span>銆?/span>


鍦?/span>鏈?/span>鐮?/span>絀?/span>涓?/span>錛?/span>閫?/span>榪?/span>灝?/span> PEOX 涓?/span>鐤?/span>姘?/span>鎬?/span>鑱?/span>鍚?/span>鐗?/span>錛?/span>渚?/span>濡?/span>鑱?/span>錛?/span>鑻?/span>涔?/span>鐑?/span>-鍏?/span>-涓?/span>鐑?/span>鑵?/span>錛?/span>錛?/span>SAN錛?/span>銆?/span>鑱?/span>錛?/span>4-涔?/span>鐑?/span>鍩?/span>鑻?/span>閰?/span>錛?/span>錛?/span>PVPh錛?/span>鍜?/span>鑱?/span>錛?/span>鍋?/span>浜?/span>姘?/span>涔?/span>鐑?/span>錛?/span>錛?/span>PVDF錛?/span>錛?/span>鍏?/span>娣?/span>鍒?/span>澶?/span>鍩?/span>浜?/span>PEOX鐨?/span>鍏?/span>娣?/span>鐗?/span>錛?/span>浠?/span>鑰?/span>鎻?/span>楂?/span>浜?/span>PEOX鐨?/span>鑰?/span>姘?/span>鎬?/span>銆?/span>閫?/span>榪?/span>璋?/span>鏁?/span>PEOX涓?/span>娣?/span>鍔?/span>鍓?/span>鑱?/span>鍚?/span>鐗?/span>鐨?/span>姣?/span>渚?/span>錛?/span>緋?/span>緇?/span>鍦?/span>鐮?/span>絀?/span>浜?/span>鍏?/span>娣?/span>鐗?/span>鐨?/span>鍖?/span>瀛?/span>鐩?/span>浜?/span>浣?/span>鐢?/span>銆?/span>褰?/span>鎬?/span>鍜?/span>閫?/span>鏄?/span>搴?/span>銆?/span>娣?/span>鍚?/span>鐗?/span>鐨?/span>鑰?/span>姘?/span>鎬?/span>鑳?/span>閫?/span>榪?/span>鎺?/span>瑙?/span>瑙?/span>銆?/span>婧?/span>瑙?/span>搴?/span>銆?/span>鍚?/span>婀?/span>鎬?/span>鍜?/span>娼?/span>婀?/span>鐜?/span>澧?/span>涓?/span>鐨?/span>鏈?/span>姊?/span>寮?/span>搴?/span>榪?/span>琛?/span>璇?/span>浼?/span>銆?/span>緇?/span>鏋?/span>琛?/span>鏄?/span>錛?/span>鑱?/span>鍚?/span>鐗?/span>鍏?/span>娣?/span>鏄?/span>鏄?/span>鎻?/span>楂?/span>浜?/span>PEOX鍦?/span>娼?/span>婀?/span>鐜?/span>澧?/span>涓?/span>鐨?/span>鑰?/span>姘?/span>鎬?/span>鍜?/span>綺?/span>闄?/span>寮?/span>搴?/span>銆?/span>涓?/span>鍏?/span>浠?/span>涓?/span>縐?/span>鍏?/span>娣?/span>鐗?/span>鐩?/span>姣?/span>錛?/span>鍚?/span>鏈?/span>30 wt% PVPh鐨?/span>鍏?/span>娣?/span>鏉?/span>鏂?/span>鍦?/span>閫?/span>鏄?/span>搴?/span>鍜?/span>鑰?/span>姘?/span>鑳?/span>鍔?/span>鏂?/span>闈?/span>琛?/span>鐜?/span>鍑?/span>浼?/span>寮?/span>鐨?/span>鎬?/span>鑳?/span>錛?/span>涓?/span>浼?/span>浜?/span>鐩?/span>鍓?/span>鏂?/span>鐚?/span>鎶?/span>閬?/span>鐨?/span>鍚?/span>綾?/span>鍨?/span>鑳?/span>綺?/span>鍓?/span>銆?/span>鍚?/span>鏃?/span>錛?/span>鍙?/span>鐜?/span>鍏?/span>娣?/span>鐗?/span>涓?/span>紼?/span>瀹?/span>鐨?/span>姘?/span>閿?/span>鍦?/span>鐤?/span>姘?/span>鏀?/span>鎬?/span>涓?/span>鍏?/span>鏈?/span>閲?/span>瑕?/span>浣?/span>鐢?/span>銆?/span>PVPh/PEOX 娣?/span>鍚?/span>鐗?/span>鍦?/span>娼?/span>婀?/span>鐜?/span>澧?/span>涓?/span>鍏?/span>鏈?/span>澧?/span>寮?/span>鐨?/span>闃?/span>姘?/span>鎬?/span>鑳?/span>錛?/span>鍏?/span>鏈?/span>浣?/span>涓?/span>鏂?/span>鍨?/span>閫?/span>鏄?/span>娑?/span>灞?/span>鎴?/span>鑳?/span>綺?/span>鍓?/span>鐨?/span>搴?/span>鐢?/span>鍓?/span>鏅?/span>銆?/span>


鍥?/span>1 鍏?/span>娣?/span>鐗?/span>SAN/PEOX, PVPh/PEOX, PVDF/PEOX钖?/span>鑶?/span>鐨?/span>SEM鍥?/span>鍍?/span>銆?/span>SAN/PEOX鍜?/span>PVDF/PEOX鐨?/span>琛?/span>闈?/span>杈?/span>涓?/span>綺?/span>緋?/span>錛?/span>PVPh/PEOX鐨?/span>琛?/span>闈?/span>鍏?/span>婊?/span>銆?/span>

濡?/span>鍥?/span>2a鎵紺?/span>錛?/span>鍏?/span>娣?/span>鐗?/span>鐨?/span>鎺?/span>瑙?/span>瑙?/span>鍧?/span>鏈?/span>鎵澧?/span>澶?/span>錛?/span>浣?/span>10s鍚?/span>SAN/PEOX鍜?/span>PVDF/PEOX鍏?/span>娣?/span>鐗?/span>鐨?/span>鎺?/span>瑙?/span>瑙?/span>榪?/span>閫?/span>鍙?/span>灝?/span>錛?/span>鑰?/span>PVPh/PEOX鍏?/span>娣?/span>鐗?/span>鐨?/span>鎺?/span>瑙?/span>瑙?/span>鍑?/span>灝?/span>鐨?/span>騫?/span>搴?/span>杈?/span>灝?/span>錛?/span>璇?/span>鏄?/span>鍏?/span>鏈?/span>涓瀹?/span>鑰?/span>姘?/span>鎬?/span>銆?/span>

鍥?/span>2 鎺?/span>瑙?/span>瑙?/span>嫻?/span>璇?/span>銆?/span>(a) PEOX鍜?/span>鍏?/span>娣?/span>鐗?/span>鍒?/span>鍒?/span>鍦?/span>嫻?/span>璇?/span>涓寮濮?/span>鍜?/span>姘?/span>婊?/span>鍋?/span>鐣?/span>10s鍚?/span>鐨?/span>鎺?/span>瑙?/span>瑙?/span>澶?/span>灝?/span>銆?/span>(b) 鎺?/span>瑙?/span>瑙?/span>鍦?/span>10 s鍚?/span>鐨?/span>鍙?/span>灝?/span>鎯?/span>鍐?/span>銆?/span>

閫?/span>榪?/span>鏀?/span>鎬?/span>涔?/span>鍚?/span>錛?/span>鏍?/span>鍝?/span>鏁?/span>浣?/span>婧?/span>瑙?/span>鐜?/span>浠?/span>瀹?/span>鍏?/span>婧?/span>瑙?/span>鍙?/span>涓?/span>閮?/span>鍒?/span>婧?/span>瑙?/span>錛?/span>鍥?/span>3a錛?/span>錛?/span>浣?/span>PEOX鍦?/span>姘?/span>涓?/span>鐨?/span>嫻?/span>鍑?/span>閲?/span>鏈?/span>鎵涓?/span>鍚?/span>錛?/span>鍥?/span>3b錛?/span>銆?/span>鍥?/span> 3c 鍜?/span> 3d 鍒?/span>鍒?/span>鏄?/span>紺?/span>浜?/span>SAN/PEOX鍜?/span>PVDF/PEOX娣?/span>鍚?/span>鐗?/span>鐨?/span> FTIR鍏?/span>璋?/span>銆?/span>嫻?/span>姘?/span>鍚?/span>錛?/span>涓?/span>縐?/span>娣?/span>鍚?/span>鐗?/span>涓?/span> PEOX鐨?/span>宄?/span>鍊?/span>鏄?/span>钁?/span>闄?/span>浣?/span>銆?/span>鐒?/span>鑰?/span>錛?/span>30PVPh/PEOX娣?/span>鍚?/span>鐗?/span>鐨?/span>寮?/span>搴?/span>鍙?/span>鍖?/span>涓?/span>澶?/span>錛?/span>鍥?/span> 3e錛?/span>錛?/span>琛?/span>鏄?/span>鍦?/span> 30PVPh/PEOX 娣?/span>鍚?/span>鐗?/span>涓?/span>淇?/span>鐣?/span>浜?/span>鏇?/span>澶?/span>鐨?/span> PEOX銆?/span>緇?/span>鏋?/span>琛?/span>鏄?/span>SAN鍜?/span>PVDF涓?/span>鑳?/span>闃?/span>姝?/span> PEOX嫻?/span>鍑?/span>鍒?/span>姘?/span>涓?/span>銆?/span>鐩?/span>姣?/span>涔?/span>涓?/span>錛?/span>PVP鍜?/span>PEOX 涔?/span>闂?/span>鐨?/span>紼?/span>瀹?/span>姘?/span>閿?/span>鍗?/span>鎹?/span>浜?/span> PEOX 鐨?/span>鏋?/span>鎬?/span>閮?/span>鍒?/span>錛?/span>鍙?/span>闃?/span>姝?/span> PEOX 嫻?/span>鍑?/span>鍒?/span>姘?/span>涓?/span>銆?/span>


鍥?/span>3 (a) 鍚?/span>縐?/span>鍏?/span>娣?/span>鐗?/span>鐨?/span>婧?/span>瑙?/span>鐜?/span>銆?/span>(b) 鍏?/span>娣?/span>鐗?/span>鍦?/span>姘?/span>涓?/span>鐨?/span>嫻?/span>鍑?/span>閲?/span>涓?/span>PEOX鍘?/span>鏈?/span>閲?/span>鐨?/span>姣?/span>鐜?/span>銆?/span>钖?/span>鑶?/span>嫻?/span>姘?/span>鍓?/span>鍚?/span>鐨?/span>綰?/span>澶?/span>鍏?/span>璋?/span>璋?/span>鍥?/span>姣?/span>杈?/span>錛?/span>(c) SAN/PEOX錛?/span>(d) PVDF/PEOX錛?/span>(e) PVPh/PEOX銆?/span>(f) 鍏?/span>娣?/span>鐗?/span>鐨?/span>鍚?/span>婀?/span>鐜?/span>銆?/span>


鐩?/span>鍏?/span>鐮?/span>絀?/span>鎴?/span>鏋?/span>浠?/span>Blending Poly(2-ethyl-2-oxazoline) with Hydrophobic Polymers as a Hybrid Adhesive with Enhanced Water-Resistant Properties涓?/span>鏍?/span>棰?/span>鍙?/span>琛?/span>浜?/span>銆?/span>Journal of Applied Polymer Science銆?/span>錛?/span>絎?/span>涓浣?/span>鑰?/span>涓?/span>瑗?/span>鍖?/span>宸?/span>涓?/span>澶?/span>瀛?/span>鏉?/span>鏂?/span>瀛?/span>闄?/span>鍗?/span>澹?/span>鐢?/span>寮?/span>濯?/span>濯?/span>錛?/span>鍏?/span>鍚?/span>閫?/span>璁?/span>浣?/span>鑰?/span>涓?/span>鏉?/span>鐐?/span>鍗?/span>鏁?/span>鎺?/span>銆?/span>欖?/span>縐?/span>搴?/span>鏁?/span>鎺?/span>銆?/span>


鐩?/span>鍏?/span>閾?/span>鎺?/span>
https://doi.org/10.1002/app.51404


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