 | 濉戞枡 | 姍¤兌 | 綰ょ淮 | 娑傛枡涓庢補澧?/a> | 鑳剁矘鍓?/a> | 澶嶅悎鏉愭枡 | 鐭沖寲 | 鍖栧伐 | 浠櫒浠〃 | 鏂頒駭涓?/a> | 涓撻 | 榪斿洖棣栭〉 |
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| 濉戞枡 | 姍¤兌 | 綰ょ淮 | 娑傛枡涓庢補澧?/a> | 鑳剁矘鍓?/a> | 澶嶅悎鏉愭枡 | 鐭沖寲 | 鍖栧伐 | 浠櫒浠〃 | 鏂頒駭涓?/a> | 涓撻 | 榪斿洖棣栭〉 |
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鍏ㄦ枃浜偣
閲戝睘鏈夋満妗嗘灦鏉愭枡錛?/span>MOF錛夊叿鏈夐珮鐨勬瘮琛ㄩ潰縐拰鍙慨楗扮殑琛ㄩ潰錛屼嬌涔嬫垚涓轟簡鏂拌兘婧愭潗鏂欓鍩熺殑鐮旂┒鐑偣涔嬩竴銆傝繎騫存潵錛?/span>MOF鍙婂叾琛嶇敓鐗╃殑鍚堟垚鍜屽簲鐢ㄥ緱鍒頒簡鐖嗙偢寮?/span>鍙戝睍錛岃騫挎硾搴旂敤浜庣數姹狅紝鍌寲錛屾皵浣撳垎紱葷瓑璇稿棰嗗煙錛岀壒鍒槸鍩轟簬MOF鍒跺鍔熻兘澶氬瓟紕崇鏉愭枡鍑熷叾浼楀浼樺娍鑰岃秺鏉ヨ秺鎴愪負鐮旂┒鐑偣銆傜劧鑰岋紝浼犵粺MOF鍒跺紕崇澶у鏁?/span>閲囩敤婀垮寲瀛︽柟娉曪紝鍚堟垚鎵嬫鍗曚竴錛屼駭閲忚緝?yōu)畯锛屾墍浣跨敤鐨勬湁鏈烘憾鍓傚鐜鏈?/span>鍗卞錛屽洜姝ゅ紑鍙戞柊鍨嬬豢鑹查珮鏁堝悎鎴愬姛鑳?/span>宸ヨ壓鍔垮湪蹇呰銆?/span>鏈爺絀朵互MOF鏉愭枡涓哄熀紜錛屽紑鍙戝嚭浜嗕竴縐嶄笉鍚屼簬浼犵粺婀垮寲瀛︽柟娉?/span>錛?/span>鍗蟲皵钂?/span>MOF絳栫暐鍚堟垚浜嗗叿鏈夊紑鏀懼瀷瀛旈亾鐨?/span>澶氬瓟紕崇鏉愭枡錛?/span>鍏惰〃鐜板嚭楂樻晥閿?/span>鍩?/span>鑳?/span>閲?/span>鍌ㄥ瓨鑳藉姏鍜岃秴楂樼殑鍖栧紼沖畾鎬?/span>錛?/span>涓鴻繘涓姝ュ悎鎴愬拰鍒╃敤鍔熻兘鍖栧瀛旀潗鏂欐彁渚涗簡鏂規(guī)硶瀛﹀拰瀹為獙鍩虹錛?/span>瀹炵幇浜嗗MOF琛嶇敓鐗╃粨鏋勩佸艦璨屽拰鎬ц兘鐨?/span>綺劇‘鎺у埗錛?/span>澶уぇ鎷撳睍浜?/span>MOF鏉愭枡鍦ㄨ兘婧愰鍩熺殑搴旂敤銆?/span>
鏃ユ湰ChEM-OIL/鍗楃澶у緪寮烘暀鎺?/span>璇鵑緇?/span>鍦ㄥ叾鍏堝墠鐮旂┒鐨勫熀紜涓?/span>錛?/span>Adv. Mater. 2016, 28, 6391; Angew. Chem. Int. Ed. 2020, 59, 7384; Adv. Mater. 2019, 31, 1904689; Angew. Chem. Int. Ed. 2020, 59, 21360; Energy Environ. Sci., 2017, 10, 1770; Nat. Rev. Mater. 2018, 3, 17075.錛夛紝紿佺牬鎬?/span>鍙戝睍浜嗕竴縐嶇畝鍗曟湁鏁堢殑鍥烘佹皵钂?/span>MOF鍚?/span>鎴愮瓥鐣ュ埗澶囦簡澹佺寮鍙ｇ殑鍔熻兘紕崇鏉愭枡銆傚惎鍙戜簬鎴戜滑鏃ュ父钂擱澶磋繃紼嬶紝鐮旂┒浜?/span>鍛橀氳繃鍒╃敤綆鍗曞浐鎬佹紓烽吀閽犵墿璐ㄥ湪鍙楃儹鏉′歡涓嬫槗鍒嗚В浜х敓紓峰寲姘㈡皵姘涘熀紜涓?/span>錛?/span>宸у鐨勫紩鍏?/span>MOF錛屽湪灝侀棴鏉′歡涓嬪MOF榪涜鈥?/span>钂?/span>鈥?/span>鐨勮繃紼嬨?/span>鎵浜х敓鐨勭７鍖栨阿姘斾綋瀵?/span>MOF榪涜鍙帶鑵愯殌錛屽啀緇忚繃榪涗竴姝ラ珮娓╃⒊鍖栧悗寰楀埌鍏峰澹佷笂寮鍙?/span>鍧囧寑姘?/span>/紓鋒幒鏉傜殑澶氬瓟紕崇鏉愭枡銆傚紑鏀懼瀷鐨勫瓟閬撹璁″彲浠ュぇ澶ф彁鍗?/span>紕崇鏉愭枡鍦ㄧ瀛愬瓨鍌ㄤ紶杈撹繃紼嬩腑鐨勪紶璐ㄦ晥鐜囷紝鑰屽湪紕蟲潗鏂欎腑鍩哄厓鍖栦綅鐐規(guī)愛/紓峰厓绱犵殑鎺烘潅鍒?/span>鏈夊埄浜庝紭鍖栭攲紱誨瓙鐨勫寲瀛﹀惛闄勶紝闄嶄綆媧誨寲澹佸瀿錛屾彁鍗囧姩鍔涘鏁堢敤銆?/span>濡傛鍙岀榻愪笅錛?/span>鍑熶互涓婁紭鍔胯鏂規(guī)硶鎵鍒跺鐨勭⒊絎兼潗鏂?/span>搴旂敤浜?/span>姘寸郴閿岀瀛愭販鍚堣秴綰х數瀹瑰櫒錛?/span>ZHSC錛?/span>浣滀負紕蟲鏋侊紝琛ㄧ幇鍑?/span>瀹界數鍘嬭繍琛岃寖鍥達紝瓚呴珮鐨勬瘮瀹歸噺/鑳介噺瀵嗗害鍜岄暱鏃墮棿寰幆瀵垮懡錛?/span>榪?/span>涓姝?/span>搴旂敤鍒?/span>杞寘鍣ㄤ歡涓紝涔熻〃鐜板嚭涓嶉敊鐨勫娓╁害鑼冨洿搴旂敤鏁堟灉錛屾弧瓚充漢浠敓浜х敓媧誨熀鏈俯搴﹂渶姹?/span>銆?/span>
鍥?/span>1. 鈥?span style="line-height:28px;font-family:寰蔣闆呴粦;">钂?/span>鈥滿OF鍒跺澹佷笂寮鍙ｇ⒊絎兼搷浣滄祦紼嬬ず鎰忓浘
紕崇鏉愭枡鐨勫彲鎺у埗澶?/strong>
灝?/span>MOF鏉愭枡鍜?/span>嬈＄７閰擱挔鍧囧寑娣峰悎澶勭悊鍚庡皝闂斁鍏ラ厤澶囨湁鐪熺┖-鍏呮皵緋葷粺鐨勭寮忕倝涓?/span>錛?/span>鍏堝崌娓╁埌300oC錛?/span>鍦ㄦ娓╁害涓嬩繚鎸佷袱涓皬鏃跺悗錛岃繘涓姝ュ崌鍒伴珮娓╁畬鎴愮⒊鍖?/span>銆?/span>300oC鏃訛紝MOF鏉愭枡淇濇寔鑹ソ錛屾鏃舵紓烽吀閽犱細閫愭鍒嗚В浜х敓紓峰寲姘㈡皵浣擄紝鍦ㄨ灝侀棴鏉′歡涓嬪MOF鏅墮潰鍙戠敓閫夋嫨鎬ц厫铓銆傝鏂規(guī)硶涓嶉渶瑕佷嬌鐢ㄤ換浣曟湁鏈烘憾鍓傦紝鐩存帴鍦ㄥ浐鎬佹潯浠朵笅鈥?span style="font-family:寰蔣闆呴粦;">鐔忚捀鈥?/span>MOF錛?/span>鏈緇堝緱鍒?/span>浜?/span>澹?/span>绔?/span>寮鍙ｇ殑澶氬瓟紕崇鏉愭枡銆傚疄楠岃〃鏄庤鏂規(guī)硶綆鍗曟湁鏁堬紝鏄竴縐嶆櫘閫傛柟娉?/span>錛?/span>鏃㈣兘瀹炵幇瀵規(guī)潗鏂欏艦璨岀殑綺劇‘鎺у埗錛?/span>鍙堣兘鏋勫緩N/P鎺烘潅鐨勯珮鏁堟椿鎬т綅鐐癸紝鍒╀簬鍖栧鍚擱檮閿岀瀛愶紝鍦ㄥ畯瑙傚拰寰涓や釜灞傞潰涓婂疄鐜頒簡鏉愭枡鐨勫畾鍚戣璁★紙鍥?/span>1鎵紺?/span>錛?/span>銆?/span>
鍥?/span>2. 鎵鍒跺紕?/span>絎兼潗鏂欒〃寰?/span>
紕崇鏉愭枡鐨勮〃寰佷笌鍌ㄨ兘搴旂敤
鎵鍚堟垚紕崇鐢?/span>SEM錛?/span>TEM錛?/span>XRD絳夊仛浜嗚〃寰?/span>錛?/span>鏂囩珷鏈変粙緇?/span>錛?/span>涓嶅璧樿堪銆?/span>鐗╃悊琛ㄥ緛璇佸疄浜嗚瓚呯粨鏋勭⒊絎兼潗鏂欑殑鎴愬姛鍚堟垚錛堝浘2鎵紺猴級銆備綔涓哄姣旓紝鐩存帴紕沖寲MOF浼氱敓鎴愯〃闈㈠畬鏁寸殑紕?/span>鏉愭枡錛屾瘮琛ㄩ潰縐皬錛屼笉鍒╀簬搴曠墿鐨勬湁鏁堜紶杈撱?/span>鍒╃敤姘旇捀MOF娉曞埗澶囩殑紕崇鏉愭枡鍛堢幇鍧囦竴鐨勫绔紑鍙ｅ艦璨岋紝鍦ㄥぇ澶ф彁鍗囦簡紕蟲潗鏂欑殑姣旇〃闈㈢Н鐨勫悓鏃訛紝瀹炵幇浜嗗鍏冨瓟寰勭殑鍒嗗竷錛屼嬌寰楁潗鏂欏湪浼犺川鍙戦潰鏁堟灉鏄捐憲銆?/span>EDS mapping璇佸疄錛屽井瑙備笂錛岃緇撴瀯琛ㄩ潰鍧囧寑鐨勫垎甯冪潃寮傚師瀛?/span>N/P鎺烘潅鐨勬椿鎬т綅鐐?/span>, 璇ユ椿鎬т綅鐐瑰彲浠ユ洿鍔犳湁鏁堢殑瀵歸攲紱誨瓙榪涜鍖栧鍚擱檮錛岄檷浣庢椿鍖栬兘鍨?/span>錛?/span>浣垮緱璇?/span>紕崇鏉愭枡鏄劇幇鍑轟紭寮傜殑閿屽熀鐢靛瓨鍌ㄦц兘銆?br />
灝嗘墍鍚堟垚鐨勭⒊絎兼潗鏂欎綔涓虹⒊姝ｆ瀬鏉愭枡搴旂敤浜庨攲紱誨瓙娣峰悎鍨嬭秴綰х數瀹瑰櫒錛?/span>ZHSC錛?/span>銆傜浉瀵逛簬鍏朵粬鍚岀瓑鏉′歡涓嬪埗澶囩殑紕?/span>鏉愭枡錛?/span>瀹為獙琛ㄦ槑錛岃繖縐嶅绔紑鍙ｇ殑N/P鎺烘潅鐨勭⒊絎兼潗鏂欒〃鐜板嚭瓚呴珮鐨勯攲鍩虹數鍖栧鍌ㄨ兘鎬ц兘鍜岄暱鏃墮棿寰幆紼沖畾鎬э紙30涓囨寰幆淇濇寔96.5%錛?/span>錛屽茍鍩轟簬姝ょ粍瑁呮垚杞寘鍣ㄤ歡鍚?/span>錛岃〃鐜板嚭浼樺紓鐨?/span>鍏?/span>鏀劇數鎬ц兘鍜?/span>瀹芥俯搴﹁寖鍥村疄鐢ㄦ晥鏋?/span>銆?/span>
緇撹涓庡睍鏈?/strong>
鏈伐浣滈嬈?/span>寮鍙戜簡涓縐嶅浐鎬佹皵鈥滆捀鈥滿OF鍒跺紕崇鏉愭枡鐨勬湁鏁堟柟娉?/span>錛?/span>寮杈熶簡涓鏉″彲鎺у悎鎴愬姛鑳?/span>澶氬瓟鏉愭枡鐨勬柊閫斿緞銆?/span>榪欓」鎴愭灉涓嶄粎鎻愪緵浜嗕竴縐嶅叏鏂扮殑絳栫暐鍚堟垚澹佷笂寮鍙ｇ殑紕崇鏉愭枡, 鏇?/span>涓轟紭鍖栬璁?/span>MOF琛嶇敓鏉愭枡鍦?/span>鐢靛寲瀛﹁兘婧愰鍩熺殑搴旂敤鎵撲笅浜嗗熀紜銆?/span>
Chun-Chao Hou, et al, A Gas-Steamed MOF Route to P-Doped Open Carbon Cages with Enhanced Zn-Ion Energy Storage Capability and Ultrastability, Angew. Chem. Int. Ed. 2021, 2101698
浣滆呯畝浠?/strong>
絎竴浣滆?/span>-渚槬鏈?/span>鍗氬＋錛?/span>
渚槬鏈濆崥澹紝浜?/span>2017涓闄㈢悊鍖栨妧鏈爺絀舵墍鑾峰緱鍗氬＋瀛︿綅錛岄殢鍚庤蕩鏃ユ湰鍔犲叆寰愬己鏁欐巿璇鵑緇勫涔犮傚凡鍦↗ACS錛?/span>Angew絳夋潅蹇楀彂琛ㄦ枃绔?/span>澶?/span>綃囷紝鐩墠涓昏浠庝簨鍩轟簬綰崇背鏉愭枡鐨勫彲鎺у悎鎴?/span>錛屽崟鍘熷瓙/鍥㈢皣鍌寲鍙婂叾鍦ㄧ數鍖栧搴旂敤絳?/span>鏂歸潰鐮旂┒銆?/span>
閫氳浣滆?/span>-寰愬己鏁欐巿錛?/span>
寰愬己鏁欐巿錛屽崡鏂圭鎶澶у璁插腑鏁欐巿錛岋紙鍓嶏級鏃ユ湰浜т笟鎶鏈患鍚堢爺絀舵墍(AIST)-浜兘澶у鍖栧鑳芥簮鏉愭枡鍒涙柊瀹為獙瀹わ紙ChEM-OIL錛変富浠?/span>錛?/span>鏃ユ湰宸ョ▼闄€佹媧茬瀛﹂櫌銆佸嵃搴﹀浗瀹剁瀛﹂櫌闄㈠＋銆備富瑕佺爺絀墮鍩熸槸綰崇背緇撴瀯鏉愭枡鐨勫寲瀛︿笌搴旂敤錛堝挨鍏舵槸鍌寲鍜岃兘婧愮瓑鏂歸潰錛夈傝縿浠婂彂琛ㄨ鏂?/span>400浣欑瘒錛岃鏂囪寮曞ぇ浜?/span>40000嬈★紝h-index >105 (Web of Science錛夈備簬2012騫磋幏寰楁堡媯礬閫忕爺絀跺墠娌垮錛?/span>Thomson Reuters Research Front Award錛夛紝2019騫磋幏媧牎濂栵紝琚?/span>Thomson Reuters / Clarivate Analytics璇勪負楂樿寮曠瀛﹀錛?/span>2014-2020騫達級銆傛媴浠誨瀹舵湡鍒婄殑緙栬緫/緙栧鍙婇【闂鍛橈紝鍖呮嫭錛?/span>EnergyChem錛?/span>Elsevier錛屼富緙栵級錛?/span>Coordination Chemistry Reviews錛?/span>Elsevier錛屽壇涓葷紪錛夛紝Chem錛?/span>Cell Press錛夛紝Matter錛?/span>Cell Press錛夛紝Chemistry-an Asian Journal錛?/span>Wiley錛?/span>, Small Structures (Wiley) 絳夈?/span>
璇鵑緇勯摼鎺ワ細http://qxulab.weebly.com/
鐩稿叧閾炬帴
https://onlinelibrary.wiley.com/doi/10.1002/adma.202101698